But DS9 clarified that most currency other than latinum is worthless because of replicator technology. That being said, we arguably have tech that can replicate cash in real life and the only reason that doesn't upend society is because government has made use of that tech illegal. So I *guess* there's no real way to answer this question without going into details on the Orion currency system and how that planet's treasures would (or wouldn't) contribute to that.
DS9 didn't really clarify anything like that.
All we gleamed from Ds9 is that Gold pressed Latinum (GPL) is used as a means of exchange between various interstellar societies in Alpha and Beta Quadrants along with trade...
Even the Ferengi didn't use GPL in their trade agreement with the Dominion - they simply decided to engage in direct trade to get their proverbial foot into the door of the Gamma Quadrant because they were greedy and wanted more profitable opportunities - to be the first and capitalize on that market).
We know UFP doesn't use money... UFP and SF have historically been seen to directly TRADE with other species (one resource for another).
UFP mainly uses GPL (or another form of currency) if/when they want to interact with societies that DO rely on currency (aka, have monetary based economy) - but even in those instances, direct trade will be dominant (and easier).
Given the size of UFP (8,000 LY's) and its tech ability, it can probably create or manufacture anything and everything it really needs with relative ease (there would be a ridiculous number of solar systems in a radii of 8,000 LY's after all)... thing is that they still want to foster good relations with other interstellar societies that DO use money... so they directly trade or use GPL to facilitate this.
Ds9 was a Bajoran space station ADMINISTERED by SF... meaning that SF still had to respect Bajoran's own economic systems and customs for the most part because it was technically their station (ahem, Bajorans took it from Cardassians, SF merely swooped in to prevent Cardassians from coming back and as we know SF RESPECTS local law and didn't/couldn't interfere into Bajoran's development too much - Bajor for the most par DID get some assistance from the Federation, but they also wanted Bajor to NOT rely too much on their aid and allow Bajorans to transform their own planet - and after about 5 odd years, they have reached the level where UFP deemed them ready to join - Sisko prevented that at the time because of the looming war with the Dominion where SF couldn't guarantee Bajor's safety).
If you remember, SF also never charged Quark anything in terms of energy use or other things (because they don't use or need money, plus Quark was of some use to them)... but SF officers on Ds9 DID participate in the local Bajoran economy (mostly to help them - but private replicator use in their personal quarters and those at work were free to use obviously - they went to Quarks and Promenade to socialize and participate, so UFP likely provided them with some GPL to participate in those activities) - and Bajor had trading agreements with the Ferengi and some other monetary based societies which visited at DS9, so a combo of trade and gold pressed Latinum was used by many - DS9 got away with it because Bajor wasn't part of UFP at the time.
Also, it was never stated that replicators can't create gold pressed Latinum. There are no canonically established limits on replicators in themselves, but we DO know that various substances are REGULATED... and as such, replicators are programmed NOT to make those substances (in other cases, large energy requirements would be another factor - on ships its less practicable to make sufficient quantities of certain substances because it would likely require massive amounts of energy to produce - in solar systems where power generation is being made on a large scale from say solar, fusion and M/AM and likely continuous, energy isn't much of a problem for making energy intensive stuff).
Take money in real life for example. It can be printed easily enough but we don't do it because it would essentially devalue it.
It is likely that the Ferengi and other interstellar powers which use GPL or other forms of currency don't replicate them for exactly the same reason - they have a whole interstellar commerce and agreements in this regard and probably do not want (at least not yet) to move past the need for currency (even if they have the tech ability to do so).
The Federation moved past money so they don't have a direct need for GPL or trading with other societies for resources, but they do engage in those aspects regardless, probably to foster good relations because trade can facilitate these and other options (plus the UFP is not a closed society).