What Happens to Oil When it is Repeatedly Heated?
In frying the oil, it is usually heated to 170-220 °C (338-428 °F). When heated to these temperatures in the presence of oxygen (air), the oil undergoes chemical reactions such as hydrolysis, oxidation, and polymerization. In other words it changes its character. Degradation products can include free fatty acids, hydro-peroxides, and polymerized triglycerides. The oil viscosity increases, its color will grow darker, and rancidity begins to develop.
What is Rancidity?
Rancidity is the decomposition of fats, oils, and other lipids through oxidation. Oxidation of fats result in the replacement of an oxygen ion with a hydrogen ion in the fatty acid molecule. This substation destabilizes the molecule and makes it possible for other odd chemical fragments to find a place along the chain. Factors which accelerate fat oxidation are trace metals (iron, zinc, copper, etc.), salt, light, water, bacteria, and molds. Oxidation occurs primarily in unsaturated fats by a free-radical-mediated process. These chemical reactions generate highly reactive molecules in rancid food which also may destroy nutrients in the food. Free radicals formed by fatty acids react with oxygen to generate peroxides that enter into a multitude of reactions, producing numerous compounds such as aldehydes, ketones, acids, esters, and polymerized fats.
Hazards of Prolonged Heating
The amounts of degradation products increase with the duration of heating at high temperatures. The toxicity of these degradation products present a health concern. Other contaminants such as polycyclic aromatic hydrocarbons may be concentrated by prolonged heating. Some of these have been found to be potential carcinogens. Certain types of plant oils such as peanut oil are sometimes contaminated by naturally occurring aflatoxin which is a human carcinogen. Peroxides and other by-products are also formed, indicating a change in the oil on a molecular level. Secondary breakdown products of peroxides and hydro-peroxides are rapidly formed by prolonged heating. Trans-fatty acids and a substance called acrylamide are also produced.