Over 99.9% of the mass of neutral antimatter is accounted for by antiprotons and antineutrons. Their annihilation with protons and neutrons is a complicated process. A proton-antiproton pair can annihilate into a number of charged and neutral relativistic pions. Neutral pions, in turn, decay almost immediately into gamma rays; charged pions travel a few tens of meters and then decay further into muons and neutrinos. Finally, the muons decay into electrons and more neutrinos. Most of the energy (about 60%) is carried away by neutrinos, which have almost no interaction with matter and thus escape into outer space.
The overall structure of energy output from an antimatter bomb is highly dependent on the amount of regular matter in the area surrounding the bomb. If the bomb is shielded by sufficient amounts of matter, the gamma rays are absorbed and the pions slow down before decaying. Part of the kinetic energy is thus transferred to the surrounding atoms, which heat up.
In any practical form however, the weapon could not simply be a ball of antimatter floating in space. There would have to be a significant amount of supporting hardware surrounding the antimatter. Also, in order to maximize the power of the bomb, it would be designed to mix the antimatter with matter in the least amount of time. The effect of a large antimatter bomb would likely be similar to that of a nuclear explosion of similar size. The reacting antimatter would release about half of its energy in a form immediately available to the environment, superheating the casing and components of the bomb and the surrounding air, and turning it into an ultrahot plasma which then emits blackbody radiation in the full EM spectrum. A quantity as small as a kilogram of antimatter would release 1.8×1017 J (180 petajoules) of energy. Given that roughly half the energy will escape as non interacting neutrinos, that gives 90 petajoules of combined blast and EM radiation, or the rough equivalent of a 20 megaton thermonuclear bomb.
http://en.wikipedia.org/wiki/Antimatter_weapon