There are potential hazards in there to be aware of. Namely resistors and such in there that can hold pants-shittingly high levels of electricity in them even when the TV is off and unplugged! This was largely true for CRT TVs and monitors and I suspect there's similar dangerous in these types of TVs too. Opening anything electronic carries very, very high levels of danger if you don't know what you are doing. Touching the wrong thing can give you a lethal jolt of electricity, again, even when the set is off and unplugged.
The only thing I can think that'd be "valuable" in it would be the bulbs for the projector which would be valuable to people with that same TV, or a TV the bulbs can work in for when their bulbs go out. Maybe the frame or mechanical bits for the bulbs to align them and such. Other than that, there's not much I think that'd be useful. The bulbs and rack should be easy get to and remove without having to worry about hurting yourself on any of the electrical components but I'm not sure "valuable" is a good word there. They're "worth money".... probably. Just not sure it'd be worth the effort.
Rather than throw it away I'd take to to a second-hand store/Goodwill and simply donate it. The Goodwill will then take care of it/decide if they can resell it. Better option than throwing it away. In lieu of either of that I'd take to an electronics store, they might be able to harvest anything in it of use or at least make sure it's disposed of properly, safely and in a manner that won't impact the environment.